Example for hme1 ;
ndd -set /dev/hme instance 1 -> further ndd commands will apply to /dev/hme1
ndd /dev/hme adv_autoneg_cap -> Are we autonegotiating? 1=true, 0=false
ndd /dev/hme link_speed -> Link speed? 1=100Mb/s, 0=10Mb/s
ndd /dev/hme link_mode -> Duplex mode? 1=FD, 0=HD
Change as appropriate :-)
You can see what speed the card has come up in /var/adm/messages
eg
Jul 4 10:45:21 florida eri: [ID 786680 kern.notice] SUNW,eri0 : 100 Mbps full duplex link up
Also check out this cool cool script. The speed and duplex setting are stored in the Kernel and can be pulled out using this script, which formats them in a nice way for you.
http://www.brandonhutchinson.com/Solaris_NIC_speed_and_duplex_settings.html
Hope this helps!